2017 届福建省厦门市高中毕业班3月质量检查考试化学试题 及答案

'www.ks5u.com2015年厦门市普通高中毕业班质量检查理综化学能力测试本卷分第I卷(选择题)和第B卷。第I卷均为必考题，第II卷包括必考和选考两部分。第I卷1一4页，第II卷5一12页，共12页。满分300分，考试时间150分钟。注意事项:1.答题前，考生务必先将自己的姓名、准考证号瑰写在答题卡上，并将准考证号条形码粘贴在答题卡上指定位置。2.答题要求，见答题卡上的“填涂举例”和“注意事项”。相对原子质原子:C-12O-16A1-27第I卷(必考)本卷共18题，每小题6分共108分。在下列各题的四个选项中，只有一个选项是正确的。6．化学家及其突出贡献为:①波义耳(化学元素概念);②道尔顿(原子学说);③门捷列夫(元素周期律);④玻尔(玻尔原子模型)。这些突出贡献提出的年代顺序是A.①②③④B.②④①③C.③①④②D.③④①②7．下列说法正确的是-14- A.乙醇和二氯甲烷都存在同分异构体B油脂在碱性条件下才能水解C制聚乙烯塑料的反应属于取代反应D.高温消毒是利用蛋白质变性的原理8．下列关于实验的说法正确的是A.将二氧化碳通人硅酸钠溶液以证明碳酸的酸性比硅酸强B.右图装置中，导管不能伸人液面的原因是产物易溶于水C.用碱石灰可干燥氯气D.用普通玻璃棒蘸取溶液做焰色反应以证明溶液含有Na十理科综合能力侧试第2页(共12页)9．甲、乙、丙是中学化学常见物质，一定条件下能发生转化:甲+强酸→乙十丙十H2O，其中乙为盐，丙为气体。下列说法正确的是A.甲一定是金属单质B.甲与乙一定含有同种元素C.丙一定是氧化物D.该反应一定是氧化还原反应10．第二周期元素X、Y、Z、W"的最高价氧化物溶于水可得四种溶液,0.010mol·L-1的这四种-14- 溶液pH与该元素原子半径的关系如右图所示。下列说法正确的是A．气态氢化物的稳定性:Z>W>YB．简单离子半径:ZP2>P3>P4B.甲醇的物质的量分数越高，反应的平衡常数越大C.若T1>T2>T3>T4，则该反应为放热反应D.T4、P4、时，H2的平衡转化率为60%第II卷必考部分第II卷必考部分共9题,157分。23．(15分)铝及其化合物用途广泛(1)铝元素的离子结构示意图为(2)下列实验能说明Al的金属性(原子失电子能力)小于Na的是(填序号)。a.分别将Na和Al同时放人冷水中b.测定等物质的量的Na和A1与酸反应生成H2的体积c.向Al(OH)3悬浊液中加人足量NaOH溶液d.用pH计测量NaCl溶液与AlC13溶液的pH(3)工业上，用冰晶石作助熔剂、石墨作电极电解熔融氧化铝制铝，每生产1吨Al，阳极大约会损失0.6吨的石墨，则石墨被氧化为(填化学式)。-14- (4)碳在高温下与Al2O3反应生成Al4C3固体与CO2该反应每转移1mol电子，吸热akJ,该反应的热化学方程式为_____。(5)室温下，往0.2mol·L-1Al2(SO4)溶液中逐滴加人1.0mol·L-1NaOH溶液，实验测得溶液pH随NaOH溶液体积变化的曲线如右图所示①a点溶液呈酸性的原因是(用离子方程式表示)_______②c→d时，A1元素的主要存在形式是(填化学式)③根据图中数据计算,A1(OH)3的KSP≈。理科综合能力测试第7页(共12页24.(15分)铜及其化合物与生产、生活关系密切。(1)用新制Cu(OH)2与葡萄糖反应制备Cu2O，该反应中葡萄糖是(填“氧化剂”或-14- “还原剂”)(2)用H2O2稀硫酸共同浸泡废印刷电路板可制备CuSO4若将该反应设计成原电池，正极的电极反应式为(3)用NH4NO3氧化海绵铜(含Cu和CuO)生产CuCl的部分流程如下:①步骤I中，反应温度不宜过高的原因是。②步骤I中，0.5molNH4NO3参加反应有4mol电子转移，铜参与反应的离子方程式为。③步骤II中，物质X可选用的物质是。(填序号)。a.Cub.C12c.H2O2d.(NH4)2SO3④步骤II中物质X需要过量的原因，其一是加快反应速率，其二是_。⑤步骤II中当NH4Cl加到一定的量时，生成CuCl会部分溶-14- 解生成CuCl2-在一定温度下建立两个平衡:CuCl(s)Cu+(aq)+Cl-(aq)Ksp=1.4x10-6CuCl(s)+Cl一(aq)CuCl2(aq)K=0.35分析[Cu+]、[CuCl2-]和Ksp,K的数学关系，在右图中画出「Cu+]、[CuCl2-]的关系曲线(要求至少标出坐标点)25.(15分)过硫酸钠(Na2S2O8)是一种重要化工原料。某研究小组进行如下实验实验一过硫酸钠的制取采用右图装置制取Na2S2O8。装置I中:主反应:(NH4)2S2O8+2NaOHNa2S2O8H+2NH3↑+2H2o副反应:①2NH3+3Na2S2O8十6NaOH===6Na2SO4+6H2o十N2②3Na2S2O8+3H2o3Na2SO4+3H2SO4+O3↑(1)装置I的作用是。(2)装置I还需补充的实验仪器或装置有_(填序号)。-14- a.温度计b.酒精灯c.水浴d.洗气瓶(3)装置I发生反应的同时需要持续通入氮气的目的是理科综合能力测试第8页〔共12页)实验二过硫酸钠的性质实验(4)为研究Na2S2O8溶解度随温度变化情况，实验过程需要测定的数据是。(5)Na2S2O8溶液与铜反应时先慢后快，除反应放热这一因素外，有人认为还有一种可能是反应生成的Cu2+对后续反应起催化作用，能检验该说法是否正确的实验方案为。实验三过硫酸钠的应用研究(6)为检验用Na2S2O8溶液吸收NO的可行性，某同学设计下图所示实验(已知NO不溶于NBOH溶液)。实验步骤如下:i检查装置气密性，并按右图加人试剂;ii打开a和d，通人足量N2，关闭d;iii.往装置中通人适量NO，关闭a;iv.....①步骤iv中，对分液漏斗的操作是_。-14- ②能证明该方案可行的实验现象是_。选考部分第II卷选考部分共5题，共35分。其中，第29、30题为物理题.第31、32为化学题.考生从两道物理题、两道化学题中各任选一题作答，若第29,30题都作答.则按第29题计分，若第31、32题都作答，则按第31题计分;第33题为生物题，是必答题。请将答案都填写在答题卡选答区域的指定位置上。31.〔化学—物质结构与性质](13分)钢铁分析中常用过硫酸盐氧化法测定钢中锰的含量，反应原理为:(1)基态锰原子的核外电子排布式为_(2)上述反应涉及的元素属干同主族元素，其第一电离能由大到小的顺序为(填元素符号)。(3)已知H2.S2O8的结构如右图。①H2.S2O8硫原子的轨道杂化方式为②上述反应中被还原的元素为。③上述反应每生成1molMnO4-S2O82-断裂的共价键类型及其数目为。-14- 理科综合能力侧试第11页(共12页)(4)一定条件下，水分子间可通过O一H...O氢键将从H2O分子结合成三维骨架结构，其中的多面体孔穴中可包容气体小分子，形成笼形水合包合物晶体①右图是一种由水分子构成的正十二面体骨架(“o”表示水分子)，其包含的氢键数为;②实验测得冰中氢键的作用能为18.8目kJ·mol-1，而冰的熔化热为5.0kJ·mol-1，其原因可能是。32.[化学—有机化学基础](13分)(l)可鉴别风信子醛和突厥酮的试剂是。(2)下列关于风信子醛和突厥酮的说法中正确的是(填序号)。a.都属于芳香族化合物b.都能使酸性高锰酸钾溶液褪色c.突厥酮的分子式为C13H20Od风信子醛不能发生加成反应-14- (3)突厥酮与嗅水反应的化学方程式为。(4)芳香烃A发生如下反应生成F:F与冬青油互为同分异构体。请回答:①若A的分子式为C10H14，则能实现上述转化的A的同分异构体有种②C→D的反应类型为。③设汁C→D和E→F步骤的目的为。④F生成高聚物的化学方程式为。-14- -14- 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