2017 届福建省三明市高三5月质量检查化学试题及答案

'福建省三明市三校2014届高三下学期联考理综化学试题本试卷分第Ⅰ卷（选择题）和第Ⅱ卷。第Ⅰ卷均为必考题，第Ⅱ卷包括必考和选考两个部分。第I卷（必考）本卷共18小题，每小题6分，共108分。一、选择题（本题共12小题。在每小题给出的四个选项中，只有一个选项符合题目要求。）7．北京2008奥运会金牌直径为70mm，厚6mm。某化学兴趣小组对金牌成分提出猜想：甲认为金牌是由纯金制造；乙认为金牌是由金银合金制成；丙认为金牌是由黄铜（铜锌合金）。为了验证他们的猜想，请你选择一种试剂证明甲、乙、丙猜想的正误A．硫酸铜溶液B.盐酸C.稀硝酸D.硝酸银溶液8．下列数据是对应物质的熔点Na2ONaClAlF3AlCl39208011291190BCl3Al2O3CO2SiO2-1072073-571723据此做出的下列判断中错误的是A．铝的化合物的晶体中有的是离子晶体B．表中只有BCl3和干冰是分子晶体C．同族元素的氧化物可形成不同类型的晶体 D．不同族元素的氧化物可形成相同类型的晶体9．将几滴KSCN（SCN-是“类卤离子”，与氯离子性质相似）溶液加入酸性的含有Fe3+的溶液中，溶液变成血红色。将该红色溶液分为两份，①一份中加入适量KMnO4溶液，红色褪去；②向另一份中通入SO2，红色也褪去。下列说法不正确的是A．①红色褪去的原因可能是KMnO4将SCN-氧化，使[Fe（SCN）]2+消失B．[Fe（SCN）]2+中Fe3+与SCN-以配位键结合。C．②红色褪去的原因是SO2具有漂白性D．SCN-在适当条件下可失去电子被氧化剂氧化为（SCN）210．下列离子方程式中正确的是A．向NaAlO2溶液中通入过量CO2：AlO2-＋CO2＋2H2O＝Al(OH)3↓＋HCO3－B．硫化钠的水解反应：S2-＋H3O+HS-＋H2OC．1mol/L的KAl（SO4）2溶液与2mol/L的Ba（OH）2溶液等体积混合：Al3++4OH—==AlO2—+2H2OD．用食醋溶解水垢：2H+＋CaCO3=Ca2+＋H2O＋CO2↑11．LiFePO4新型锂离子动力电池以其独特的优势成为奥运会绿色能的新宠。已知该电池放电时的电极反应式为：正极FePO4+Li++e-==LiFePO4负极Li－e-==Li+下列说法中正确的是A．充电时电池反应为FePO4+Li=LiFePO4B．充电时动力电池上标注“+”的电极应与外接电的正极相连 C．放电时电池内部Li+向负极移动D．放电时，在正极上是Li+得电子被还原12．将0.1mol/L的醋酸钠溶液20mL与0.1mol/L盐酸10rnL混合后，溶液显酸性，则溶液中有关微粒的浓度关系正确的是A．c(Ac-)＞c(Cl-)＞c(H+)＞c(HAc)B．c(Na+)＋c(H+)＝c(Ac-)＋c(Cl-)C．c(Ac-)＝c(Cl-)＞c(H+)＞c(HAc)D．c(Ac-)＞c(Cl-)＞c(HAc)＞c（H+）23．（12分）D、A、B、C为四种原子序数依次增大的短周期元素，A、B、C同周期，A的原子半径是同周期中最大的；B、D同主族。已知D元素的一种单质是日常生活中饮水机常用的消毒剂，C元素的单质可以从A、B两元素组成的化合物的水溶液中置换出B元素的单质。（1）C元素在周期表中的位置周期族。（2）A、B元素形成的常见化合物水溶液显性，原因是（用离子方程式表示）；用石墨做电极电解该化合物的水溶液，则阴极反应式为，（3）A、D元素可以形成化合物A2D2，写出A2D2与CO2反应的化学方程式（用元素符号表示）。该反应中还原剂是。 （4）B元素的单质在不同的条件下可以与O2发生一系列反应：B(s)+O2(g)=BO2(g)；△H=－296.8kJ·mol－12BO2(g)+O2(g)2BO3(g)；△H=－196.6kJ·mol－1则1molBO3(g)若完全分解成B（s），反应过程中的热效应为。24．（16分）实验室模拟合成氨和氨催化氧化的流程如下：（1）已知实验室可用饱和亚硝酸钠（NaNO2）溶液与饱和氯化铵溶液经加热后反应制取氮气,该反应中只有氮元素发生变价，写出该反应的化学方程式。从下图中选择制取氮气的合适装置。（2）氮气和氢气通过甲装置，甲装置的作用除了将气体混合外，还有。 （3）用乙装置吸收一段时间氨后，再通入空气，同时将经加热的铂丝插入乙装置的锥形瓶内，能使铂丝保持红热的原因是：，锥形瓶中还可观察到的现象是：。（4）反应结束后锥形瓶内的溶液中含有H+、OH-、离子。25．（10分）工业上以黄铁矿为原料生产硫酸主要分为三个阶段进行，即煅烧、催化氧化、吸收。请回答下列个问题：（1）煅烧黄铁矿形成的炉气必须经除尘、洗涤、干燥后进入（填设备名称）（2）催化氧化阶段反应2SO2(g)+O2(g)2SO3(g)；△H＜0550℃时，SO2转化为SO3的平衡转化率（α）与体系总压强（p）的关系如右图所示。理论上要提高SO2的转化率，反应的条件应是温、高压（填“高”、“低”、或“常”），但通常情况下工业生产中采用常压的原因是。 将2.0molSO2和1.0molO2置于5Ｌ密闭容器中，反应达平衡后，体系总压强为0.10MPa。该反应的平衡常数等于。（3）为循环利用催化剂，科研人员最新研制了一种离子交换法回收钒的新工艺，回收率达91.7%以上。已知废钒催化剂中含有V2O5、VOSO4及不溶性残渣。查阅资料知：VOSO4可溶于水，V2O5难溶于水，NH4VO3难溶于水。该工艺的流程如下图。废钒催化剂（主要含VOSO4、V2O5）①Na2SO3/H2SO4粉碎、水浸过滤滤液滤渣离子交换还原、酸浸、过滤滤渣滤液KClO3NH4Cl反应③焙烧V2O5反应②(VO2)2SO4NH4VO3调节pH为8VO3—反应④则：反应①②③④中属于氧化还原反应的是（填数字序号），反应③的离子方程式为。该工艺中反应③的沉淀率（又称沉矾率）是回收钒的关键之一，沉钒率的高低除受溶液pH影响外，还需要控制氯化铵系数(NH4Cl加入质量与料液中V2O5的质量比)和温度。根据下图试建议控制氯化铵系数和温度：、。 30．（化学——物质结构与性质，13分）下面的表格是元素周期表的一部分，其中的字母对应不同的元素。AMQREDGJ请回答下列问题：（1）G和J形成的合金是一种贮氢材料，其晶体结构与氯化铯相同。该合金中每个G原子周围与其最近且等距的J原子有个。该晶体属于晶体A.离子晶体B.原子晶体C.分子晶体D.金属晶体（2）M3R2是一种直线型分子R=M=M=M=R，该分子是一种分子（填极性或非极性）。（3）请写出D-的电子排布式：。（4）M2A2也是直线型分子，1个分子中含有个σ键。（5）化合物E2D6分子中各原子均达到了八电子稳定结构，请画出其结构式。（用元素符号表示） 31．（化学——有机化学基础，13分）由丙烯经下列反应可得到F、G两种高分子化合物，它们都是常用的塑料。（1）判断以下过程的反应类型：A→BD→E（2）聚合物F的结构简式是_____________________________________。（3）B转化为C的化学方程式是__________________________________________________。（4）在一定条件下，两分子E能脱去两分子水形成一种六元环化合物，该化合物的结构简式是_________________________________________。（5）E有多种同分异构体，其中一种能发生银镜反应，1mol该种同分异构体与足量的金属钠反应产生1molH2，则该种同分异构体为_____________________________________。理科综合能力测试参考答案 24.（15分）△（1）NaNO2+NH4Cl==NaCl+N2↑+2H2O（3分）a（2分）（2）干燥气体（2分）控制氢气和氮气的流速 （2分）（3）说明氨的氧化反应是一个放热反应（2分）有红棕色气体产生（2分）（4）（2分）25．（15分）（1）接触室（1分）（2）低（2分）使用常压SO2就可以达到较高的转化率。（2分）400L·mol—1，（2分）（4）①②（2分）NH4++VO3-==NH4VO3↓(2分)4和80℃。 （各2分，共4分）30．（13分）（1）8（2分）D（2分）（2）非极性（2分）（3）1s22s22p63s23p6（2分）（4）3（2分）（5）(3分)31．（13分）（1）取代（或水解）；加成（或还原）（各1分，共2分）（2）（2分）（3）(3分) 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