2016届福建省龙岩市高三下学期3月教学质量检查化学试题及答案

'龙岩市2014年高中毕业班教学质量检查化学测试(考试时间：150分钟；满分：300分)本试卷分为第Ⅰ卷{选择题)和第Ⅱ卷(非选择题)。第Ⅰ卷为必考题。第Ⅱ卷包括必考题和选考题两部分。本试卷共12页。满分300分，考试时间150分钟。注意事项：l．答题前．考生务必先将自已的姓名填写在答题卡上。2．考生做答时．请将答案答在答题卡上，在本试卷上答题无效；按照题号在各题的答题区域内作答，超出答题区域书写的答案无效。3．选择题答案必须使用2B铅笔填涂，如需改动用橡皮擦干净后．再选涂其它答案标号；非选择题必须使用0.5毫米黑色字迹的签字笔书写，字体工整、字迹清楚。4．做选考题时，请考生按照题目要求作答。请按照题号在答题卡各题目的答题区域内作答，超出答题区域书写的答案无效。5．保持卡面清洁，不要折叠、不要弄破、弄皱，不准使用涂改液、刮纸刀。第Ⅰ卷(选择题共108分)本卷共18小题．每小题6分．共108分。在每小题给出的四个选项中，只有一个选项符合题目要求。6．既能用浓硫酸又能用碱石灰干燥的气体是 A．Cl2B．SO2C．COD．NH37．在pH=0的溶液中能大量共存的离子组是A．Fe3+，K+，SO42-，I-B．Mg2+，NH4+，NO3-，Cl-C．Na+，K+，SO42-，Al(OH)4一D．Ba2+，Na+，NO3-，CO32-8．化合物X(分子式为C2H6O)具有如下性质：X+Na→慢慢产生气泡；X+乙→有香味产物Y。以下判断正确的是A．X的结构简式为CH3OCH3B．香味产物分子式为C4H10O3C．x可由乙烯通过加成反应制得D．X、Y和乙酸均能与烧碱反应9．下列根据化学事实进行的相关推论，正确的是10．科技工作者提出用铝粉处理含亚硝酸盐废水的思路：调节亚硝酸盐废水酸碱性，使其pH>12，然后加入适量的铝粉、搅拌，从而实现预期且的。下列判断错误的是A．废水处理时铝单质转化为Al3+B．废水处理中，亚硝酸盐被还原C．处理过程中，OH一参与了反应D．铝粉颗粒大小影响废水处理的速率11．硫代硫酸钠(Na2S2O3 )溶液与盐酸混合，生成单质硫并沉淀出来。若将硫代硫酸钠溶液先与界面活性剂(不参与反应)均匀混合于烧杯中，再加人盐酸溶液并立刻搅拌，静置后无沉淀产生，得到含硫单质的腔体(硫分散在体系中)。下列叙述错误的是A．界面活性剂减缓了硫生成的速率B．烧杯中单质硫颗粒直径约为10-9-10-7mC．硫代硫酸钠与盐酸反应中，盐酸作氧化剂D．用平行光照射烧杯中液体，将观察到光的“通路”12．用某浓度NaOH溶液滴定一元酸HA的滴定曲线如图所示(横坐标为滴入NaOH的体积，纵坐标为所得混合液的pH；甲基橙变色范围为3.1一4.4)。下列判断正确的是A．HA的浓度为l×10-4mol·L-1B．实验时可选甲基橙作指示剂C．V=10mL，酸碱恰好中和D．pH=7时，溶液中c(Na+)>c（A-）第Ⅱ卷(必考部分共10题157分)23．(17分)I．短周期元素X、Y、Z、W在元素周期表中相对位置如图所示 其中Y所处的周期序数与族序数相等。按要求回答下列问题：(1)写出X的原子结构示意图_______________。(2)列举一个事实说明W非金属性强于Z:_______________(用化学方程式表示)(3)含Y的某种盐常用作净水剂，其净水原理是__________(用离子方程式表示)II．运用所学化学原理，解决下列问题：(4)已知：Si+2NaOH+H2O=Na2SiO3，+2H2。某同学利用单质硅和铁为电极材料设计原电池(NaOH为电解质溶液)，该原电池负极的电极反应式为_________________;(5)已知：①C(s)+O2(g)=CO2(g)H=akJ·mol-1；②CO2(g)+C(s)=2CO(g)H=bkJ·mol-1；③Si(s)+O2(g)=SiO2(s)H=ckJ·mol-1。工业上生产粗硅的热化学方程式为__________________________________________;(6)已知：CO(g)+H2O(g)H2(g)+CO2(g)。右表为该反应在不同温度时的平衡常数。则：该反应的H____0(填“<”或“>”)；500℃时进行该反应，且CO和H2O起始浓度相等，c0平衡转化率为。24．(13分)CuCl2溶液中的铜主要以Cu(H2O)42+、CuCl42- 形式存在，它们间有如下转化关系：Cu(H2O)42+(蓝色)+4Cl-CuCl42-(黄色)+4H2O；电解不同浓度的CuCl2溶液，均可看做Cu2+、Cl-直接放电。下图为电解浓度较大CuCl2溶液的装置，实验开始后，观察到丙中的KI-淀粉溶液慢慢变蓝。回答下列问题：(1)甲电极的电极反应式为_________________。(2)丙中溶液变蓝是乙电极产物与KI反应导致的，该反应的化学方程式为_________________。(3)随电解的不断进行，U型管中溶液的颜色变化为__________;A．由黄色变为浅蓝色B．由蓝色变为浅黄色溶液颜色变化的原因是_________________。(4)当电解到一定程度，甲电极附近出现蓝色Cu(OH)2絮状物。经测，甲电极附近溶液的pH=a，此时甲电极附近郴c(Cu2+)=______mol·L-1。(已知：Cu(OH)2的Ksp=2.2*10-20)。(5)电解较长时间后，丙中溶液的蓝色又会褪去，这是因为乙电极产物进一步将I2氧化为IO3-。该反应的离子方程式为______________。25．(15分)　　实验室可用MnO2和KClO3 混合加热的方法制取氧气：I．现有下列仪器或装置：(1)A－D装置中，用作KClO3为原料制氧气的反应装置是＿＿＿＿(填序号)。(2)排水法收集氧气，接口顺序是：氧气出口→___→___→g→h→烧杯(填序号)。Ⅱ．KClO3分解时尚有副反应，导致收集到的气体有异味。据推测，副产物可能是O3、Cl2、ClO2 中的一种或几种。资料表明：O3、Cl2、ClO2的沸点依次为-111℃、-34℃和11℃，且O3、ClO2也能将KI氧化为I2。为探究副反应气体产物的成分，将KClO3分解产生的气体经干燥后通入如右装置进行实验：(3)若要确认副产物中含Cl2，F中应盛放_____溶液。(4)确定副产物中含有ClO2的现象是_________________。(5)实验时若D中无现象，E中试纸变蓝，能否得出副产物含有凸的结论?答：_____(填“能”或“不能”)。理由是________________________________。Ⅲ．ClO2是饮用水消毒剂。用ClO2处理过的饮用水(pH为5.5~6.5)除含有ClO2外，常含有一定量对人体不利的ClO2-。为测定此饮用水中两者成分，进行如下实验：准确量取vmL水样加入到锥形瓶中，调节水样pH=8，加人足量KI晶体，发生如下反应：2ClO2+2I-=I2+2ClO2-，反应结束后产生amolI2；继续调节溶液pH=1，又发生如下反应：ClO2-+4H+=2I2+Cl-+2H2O，反应结束后叉产生bmolI2。(6)饮用水中c(ClO2-)=_____________mol·L-1(用含字母的代数式表示)。 第Ⅱ卷(选考部分共5题35分)第Ⅱ卷选考部分共5题，共35分。其中，第29、30题为物理题．第31、32题为化学题。考生从两道物理题、两道化学题中各任选一题作答．若第29、30题都作答．则按第29题计分，若第31、32题都作答．则按第31题计分；第33题为生物题，是必答题。请将答案都填写在答题卡选答区域的指定位置上。3l．(13分)【化学—物质结构与性质】氯化硼(BN)晶体是一种新型无机合成材料。用硼砂(Na2B4O7)和尿素反应可以得到氮化硼：Na2B4O7+2CO(NH2)2=4BN+Na2O+4H2O+2CO2↑根据要求回答下列问题：(1)组成反应物的所有元素中，第一电离能最大的是___________________。(2)尿素分子()中键与键数目之比为__________；尿素分子中处于同一平面的原子最多有_______个。(3)尿素分子一定条件下形成六角形“超分子”（结构如图）。“超分子”中尿素分子间=主要通过什么作用力结合。答：________________(填1种)。(4)图示“超分子”的纵轴方向有一“通道”。直链烷烃分子刚好能进人通道．并形成“超分子” 的包台物；支链烷烃因含有测链，空间体积较大而无法进入“通道”。利用这一性质可以实现直链烷烃和支链烷烃的分离。①直链烷烷烃分子能进人通道时，通过什么作用力与“超分子”结合，从而形成“超分子”包合物?答：___________________。②下列物质可以通过尿素“超分子”进行分离的是____________。A．乙烷和丁烷B．丁烷和异丁烷C．异戊烷和新戊烷D氯化钠和氯化钾(5)BN晶体有a、B两种类型，且a—BN结构与石墨相似、B—BN结构与金刚石相似。①a一BN晶体中N原子杂化方式是____________________;②B—BN晶体中，每个硼原予形成________个共价键。这些共价键中，有________个为配位键。32．(13分)【化学一有机化学基础】已知有机物A—F具有如下的转化关系。根据要求填空：(1)A中的含氧官能团有___________________(写名称)，A的分子式为______________。(2)A转化生成B的反应类型是_________________。(3)C转化生成D的试剂和条件_________________。 (4)F在酸性条件下水解的化学方程式为_________________。(5)A的同分异构体R，具有如图所示的性质。请写出符合条件的R的同分异构体的结构简式（任写两种）。 龙岩市2014年高中毕业班教学质量检查理科综合能力测试答案第Ⅰ卷（选择题共108分）本卷共18小题，每小题6分，共108分。在每小题给出的四个选项中，只有一个选项符合题目要求。题号6789答案CBCD题号101112答案ACC第Ⅱ卷（必考部分共10题157分）23．（17分）（1）（2分）（2）2HClO4+Na2SiO3=2NaClO4+H2SiO3↓（3分）（3）Al3++3H2OAl(OH)3+3H+（2分）（4）Si-4e-+6OH-=SiO32-+3H2O（3分）（5）2C(s)+SiO2(s)=Si(s)+2CO(g)△H=(a+b-c)kJ·mol-1与教材表示法一致，斜体。（3分）（6）＜（1分）75％（3分）24．（13分）（1）Cu2++2e-=Cu（2分）（2）Cl2+2KI=2KCl+I2（2分）（3）A（1分）随电解进行，Cl—不断消耗，CuCl42-转化为Cu(H2O)42+（2分）（4）2.2×10(8-2a)（3分）（5）5Cl2+I2+6H2O=10Cl-+2IO3-+12H+（3分）25．（15分）（1）A（2分）（2）f、e（2分）（3）AgNO3溶液（2分，其他合理答案也可）（4）C装置试管中有液体生成（3分）（5）不能（1分）Cl2也可以氧化KI产生I2（2分）（6）1000×(0.5b-2a)/v（3分）第Ⅱ卷（选考部分共5题35分） 31．（13分）（1）N（2分）（2）1︰7（2分）6（2分）（3）氢键（2分）（4）①范德华力（1分）②B（1分）（5）①sp2（1分）②41（各1分，共2分）32．（13分）（1）羧基、羟基（每个1分，共2分）C9H10O3（1分）（2）缩聚（1分）（3）NaOH/醇溶液（加热）、酸化（2分，未答“酸化”也不扣分）（4）（3分）（5）（每个2分，共4分；其他合理答案也可给分）内部资料仅供参考9JWKffwvG#tYM*Jg&6a*CZ7H$dq8KqqfHVZFedswSyXTy#&QA9wkxFyeQ^!djs#XuyUP2kNXp6X4NGpP$vSTT#UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmUE9aQ@Gn8xp$R#͑Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z8vG#tYM*Jg&6a*CZ7H$dq8KqqfHVZFedswSyXTy#&QA9wkxFyeQ^!djs#XuyUP2kNXpRWXmA&UE9aQ@Gn8xp$R#͑Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z8vG#tYM*Jg&6a*CZ7H$dq8KqqfHVZFedswSyXTy#&QA9wkxFyeQ^!djs#XuyUP2kNXpRWXmA&UE9aQ@Gn8xp$R#͑Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmUE9aQ@Gn8xp$R#͑Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNuGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$U*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89Amv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$U*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz84!z89Amv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$U*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$U*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNuGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5ux^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#&ksv*3tnGK8!z89AmYWv*3tnGK8!z89AmYWpazadNu##KN&MuWFA5uxY7JnD6YWRrWwc^vR9CpbK!zn%Mz849Gx^Gjqv^$UE9wEwZ#Qc@UE%&qYp@Eh5pDx2zVkum&gTXRm6X4NGpP$vSTT#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