2018年福建省普通高中毕业班4月质量检查化学试题及答案

'2015年福建省普通高中毕业班质量检查理科综合能力　化学测试6.下列工业生产的主要反应中，涉及置换反应的是A.制取粗硅　　B.海水提镁　　C.电解制铝　　D.制备硫酸7.设NA为阿伏加德罗常数的值，下列说法正确的是A.18gH20中含NA个质子B.1L1mol·L一1的CuSO4溶液中含NA个Cu2＋C.常温常压下，2.24LCl2中含0.2NA个氯原子D.0.5molAl与足量NaOH溶液充分反应，转移的电子数目为1.5NA8.有机物甲、乙、丙（CH3COOC2H5）、丁(CH3CHO）与乙醇的转化关系如右图所示。下列判断不正确的是A.甲是乙烯　　　　　　　　　　　　B.乙可能是葡萄糖C.丙与NaOH溶液反应不能生成乙醇　D.丁十H2→乙醇的反应属于加成反应9.下列溶液中，一定呈中性的是·13· A.由非电解质溶于水得到的溶液　B.均为的溶液C.等物质的量的强酸与强碱反应得到的溶液　D.将pH=9的烧碱溶液稀释100倍所得到的溶液10.分别向含有下列离子的溶液中通入足量NO2气体，数目不会减少的是11．实验室中，从海带中提取I2的实验流程如下图所示，下列说法不正确的是A:操作①用到的玻璃仪器有：烧杯、玻璃棒、漏斗B.操作②中需加入氧化剂C.可以用四氯化碳或酒精代替苯作萃取剂D.蒸馏I2的苯溶液可获取I2并回收苯12.往某恒温密闭容器中加入CaCO3，发生反应：反应达到平衡后，t1时，缩小容器体积，x随时间（t）变化的关系如右图所示。x不可能是·13· A.v逆　B.c(CO2)C.D.（容器内气体密度）23.（14分）甲、乙、丙三种物质均由短周期元素组成，一定条件下，存在下列转化关系：甲＋乙→丙+H20（1)若丙为Na2C03，反应的化学方程式为　　　　　　　（任写一个）。溶液中，所含的离子按物质的量浓度由大到小的顺序排列为　　　　。(2)若甲是石油裂解气的主要成分之一，乙为O2，且甲分子和乙分子具有相同的电子数。25℃、101kPa时，1g甲完全燃烧生成CO2气体与液态水，放出50.5kJ的热量，该反应的热化学方程式为　　　　　　　　　　；利用该反应设计的燃料电池中，通入·13· 甲的电极为电池的　　　　　　（填“正极”或“负极”）。(3）若甲、乙是同主族元素的氢化物，丙为单质。①丙所含元素在元素周期表中的位置为　　　　　　②甲与水相比，热稳定性较强的是　　　　　　（填化学式）。24.（15分）软锰矿（主要成分为Mn02）可用于制备锰及其化合物。（1)早期冶炼金属锰的一种方法是先缎烧软锰矿生成Mn304，再利用铝热反应原理由Mn3O4制备锰。该铝热反应的化学方程式为　　　　　　（2)现代冶炼金属锰的一种工艺流程如下图所示：①软锰矿还原浸出的反应为：·13· 该反应中，还原剂为　　　　。写出一种能提高还原浸出速率的措施：　　　　②滤液1的pH　　　　（填“＞”“＜”或“＝”）MnS04浸出液的pH.③加入MnF2的目的是除去　　　　（”）。（3）由MnS04制取MnC03。往MnS04溶液中加人NH4HC03溶液，析出MnC03沉淀并逸出C02气体，该反应的离子方程式为　　　　　　　　　　；若往MnS04溶液中加人（NH4）2C03溶液，还会产生Mn(OH)2，可能的原因有：，t℃时，该反应的平衡常数K＝　　　　（填数值）。25.（16分）某化学兴趣小组进行有关电解食盐水的探究实验，电解装置如右图所示。·13· 实验一：电解饱和食盐水。（1)简述配制饱和食盐水的操作：　　　　　　　　　　　（2）电解饱和食盐水的离子方程式为　　　　　　　　　　　实验二：电解不饱和食盐水及产物分析。相同条件下，电解1mol·L一1NaCl溶液并收集两极产生的气体。在X处收集到V1mL气体，同时，在Y处收集到V2mL气体，停止电解。结果发现V2＜V1，且与电解饱和食盐水相比，Y处收集到的气体颜色明显较浅。经讨论分析，导致上述现象的原因有：i．有部分C12溶解于NaCl溶液中；ii．有02生成。(3）设计实验证明有部分C12溶解于NaCl溶液中。实验方案为　　　　　　　。（4）证明有O2生成并测定O2的体积。按如右图所示装置进行实验。通过注射器缓缓地将在Y处收集到的V2mL气体全部推入装置A(盛有足量试剂）中，最终，量气管中收集到V3mL气体（设均在相同条件下测得）。·13· ①装置A的作用是　　　　　。②本实验中，观察到　　　　的现象，说明石墨电极上有02生成。③实验中是否需要预先除净装置中的空气？　　　　（填“是”或“否”）。(5)实验二中，在石墨电极上生成Cl2的总体积为　　　　　mL（用代数式表示）。实验反思：(6)由以上实验推知，欲通过电解食盐水持续地获得较纯净的氯气，电解时应控制的条件：①　　　　　　；②　　　　　　　。要进一步证明该推论，还需进行电解不同浓度食盐水的平行实验。31．［化学—物质结构与性质〕（13分）硅、锗、磷化锢、氮化镓、聚丙烯睛都是半导体材料。（1)基态锗（Ge)原子的核外电子排布式为　　　　　。(2)聚丙烯睛由丙烯睛（CH2＝CH－CN）聚合而成。丙烯睛分子中所有原子都在同一平面上，则丙烯睛分子中，碳原子的杂化轨道类型有　　，的个数比为　　　。(3)（CH3)3Ga、(CH3CH2)3·13· Ga是制取氮化稼的常见镓源，常温常压下均为无色透明的液体。下列说法正确的是　　　　（填标号）。A.（CH3）3Ga晶体属于分子晶体B.（CH3）3Ga中所含化学键都是极性键C.（CH3CH2）3Ga晶体中含有氢键D.（CH3CH2）3Ga中所有原子都达到稀有气体的稳定结构(4)氮化稼（GaN）的晶体结构如左下图所示。该晶体中　　　　　（填“有”或“无”）配位键存在，判断的依据是　　　　　(5)右上图表示碳、硅和磷元素的四级电离能变化趋势，其中表示磷的曲线是＿　　（填标号）。32.［化学—有机化学基础〕（13分）尼泊金甲醋和香兰素在食品、化妆品行业有广泛用途。它们的结构简式如下：·13· （1)尼泊金甲醋中显酸性的官能团是　　　　　（填名称）。　(2)下列说法中，正确的是　　　　（填标号）。A.尼泊金甲醋和香兰素分子式都是C8H803B.尼泊金甲醋和香兰素都能发生水解反应C.1mol尼泊金甲酷或香兰素均能与4molH2发生加成反应D.利用银氨溶液可以鉴别尼泊金甲酷和香兰素(3)大茴香酸与香兰素互为同分异构体，它是一种梭酸，且具备以下3个特点。大茴香酸的结构简式为　　　　　　。a.分子中含有甲基　b.遇FeC13溶液不显紫色　c.苯环上的一氯代物只有两种(4）以丁香油酚为原料，通过下列路线合成香兰素。·13· （注：分离方法和其他产物已经略去；乙酸酐的结构简式为）①由合成丁香油酚的反应类型为　　　　。②步骤II中，反应的化学方程式为　　　　　③W的结构简式为　　　　　　·13· 化学答案·13· 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